From: "Saved by Windows Internet Explorer 7" Subject: Safety (MSDS) data for iodine Date: Sat, 17 May 2008 16:38:58 -0400 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_0000_01C8B83C.8132FC90" X-MimeOLE: Produced By Microsoft MimeOLE V6.0.6000.16545 This is a multi-part message in MIME format. ------=_NextPart_000_0000_01C8B83C.8132FC90 Content-Type: text/html; charset="utf-8" Content-Transfer-Encoding: quoted-printable Content-Location: http://msds.chem.ox.ac.uk/IO/iodine.html =EF=BB=BF Safety (MSDS) data for iodine  =20

Safety data for iodine

3D"Hazard: 3D"Hazard: 3D"Hazard:

Click here for data on iodine in studen= t-friendly=20 format, from the HSci project

Glossary=20 of terms on this data sheet.=20

The information on this web page is provided to help you to work = safely, but=20 it is intended to be an overview of hazards, not a replacement for a = full=20 Material Safety Data Sheet (MSDS). MSDS forms can be downloaded from the = web=20 sites of many chemical suppliers.

General

Physical data

Appearance: Purple to black crystals
Melting point: 113 - 114 C=20
Boiling point: 183 C
Specific gravity: 4.93
Vapour pressure: = 0.31 mm=20 Hg at 25 C
Vapour density: 9.0 (air =3D 1)
Flash point: n/a =
Explosion=20 limits: n/a
Autoignition temperature:

Stability

Stable. Oxidizer. Substances to be avoided include strong reducing = agents,=20 powdered metals, ammonia, ammonium salts, acetylene, acetaldehyde, = combustible=20 materials, aluminium, chemically active metals, carbides, turpentine = oils,=20 azides, carbides, ammonium hydroxide, sodium thiosulfate. Sublimes = slightly at=20 room temperature.

Toxicology

Toxic - may be fatal if swallowed or inhaled. Corrosive, causes = burns.=20 Harmful by inhalation and through skin absorption. UK OES short-term 1 = mg/m3=20 (0.1 ppm). Readily absorbed through skin. Very destructive of mucous = membranes=20 and upper respiratory tract, eyes and skin. Severe irritant. Sublimes at = room=20 temperature to yield dangerous levels of vapour. May cause = sensitization. May=20 cause damage to the unborn child.=20

Toxicity data
(The meaning of = any=20 abbreviations which appear in this section is given here.)= =20
ORL-HMN LDLO 28 mg kg-1
ORL-RAT LD50 14000 mg = kg-1=20 (? Although quoted by a reputable chemical supplier, this value looks=20 unreasonably high compared to that given for humans. However, the same = supplier=20 quotes an ORL-MUS LD50 of 22000 mg kg-1, and ORL-RBT LD50 of = 10000 mg=20 kg-1.)
UNR-MAN LDLO 29 mg kg-1=20

Risk phrases
(The meaning of = any risk=20 phrases which appear in this section is given here.)
R20 = R21 R50.=20 [Note: Annex I does not give R34, corrosive, as a risk phrase. However, = this=20 material is corrosive in contact with the skin and should be handled as = though=20 R34 is specified. Furthermore, R20 and R21 are quoted rather than R23 = and R24,=20 even though some sources list this material as toxic.]

Environmental information

Transport information

Personal protection

Safety glasses, nitrile gloves. Effective ventilation.=20

Safety phrases
(The meaning = of any=20 safety phrases which appear in this section is given here.) =
S23=20 S25.

[Return to Physical &=20 Theoretical Chemistry Lab. Safety home page.]=20

This information was last updated on April 3, 2008. Although we have = tried to=20 make it as accurate and useful as possible, we can take no = responsibility for=20 its use or misuse.=20

Note also that the information on the PTCL = Safety web=20 site, where this page was hosted, has been copied onto many other sites, = often=20 without permission. If you have any doubts about the veracity of the = information=20 that you are viewing, or have any queries, please check the URL that = your web=20 browser displays for this page. If the URL begins=20 "http://msds.chem.ox.ac.uk/" the page is maintained by the Safety = Officer in=20 Physical Chemistry at Oxford University. If not, this page is a copy = made by=20 some other person and we have no responsibility for it.

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